THERMAL O17

Solution Q17

Analysis

We are given a mono-atomic gas (Degrees of freedom $f=3$, $C_V = \frac{3R}{2}$) undergoing a process where the molar specific heat is $C = 2R$.

The general formula for molar heat capacity in a polytropic process $PV^x = \text{constant}$ is given by:

$$ C = C_V + \frac{R}{1-x} $$

Substituting the given values:

$$ 2R = \frac{3R}{2} + \frac{R}{1-x} $$ $$ \frac{R}{2} = \frac{R}{1-x} \implies 1-x = 2 \implies x = -1 $$

So the process follows the equation $PV^{-1} = \text{constant}$, which implies $P \propto V$.

Temperature-Volume Relationship

Using the ideal gas equation $PV = nRT$, we can substitute $P \propto \frac{T}{V}$ into the process equation:

$$ \left(\frac{T}{V}\right) V^{-1} = \text{constant} \quad \text{(Incorrect substitution)} $$

Let’s use the standard relation for polytropic process $TV^{x-1} = \text{constant}$:

$$ T V^{-1-1} = \text{constant} \implies T V^{-2} = \text{constant} $$ $$ T \propto V^2 $$

Alternatively, since $P \propto V$, substituting into $PV \propto T$ gives $(V)V \propto T \implies V^2 \propto T$.

Calculation

The volume is doubled: $V_f = 2V_i$.

$$ \frac{T_f}{T_i} = \left( \frac{V_f}{V_i} \right)^2 = (2)^2 = 4 $$

Thus, the temperature becomes 4 times the initial temperature.

V T State 1 State 2 (2V, 4T)

Correct Option: (d) 4