THERMAL CYU 29

Thermodynamic Cycle Solution

Corrected Diagram

V / m³ p / Pa 0 0 A B C D 1 2 3

Analysis of the Cyclic Process

Let the initial state at point $A$ be $(V_0, P_0)$ with temperature $T_0$.

1. Establishing the Coordinates

From the problem statement and diagram geometry:

  • Points $A$, $2$, and $C$ lie on a diagonal through the origin, implying linear proportionality.
  • Points $B$, $2$, and $D$ lie on an isotherm (dashed curve), meaning they share the same temperature.

Let $T_B = T_D = T_2$. Since $B$ and $D$ form the corners of a rectangle with $A$, and lie on the same isotherm, the cycle is symmetric. If we assume the standard setup where $T_{max} = 16 T_{min}$ (a common variation of this problem):

  • $T_A = T_0$ (Minimum)
  • $T_C = 16 T_0$ (Maximum)

Using the Ideal Gas Law $PV \propto T$, this implies $P_C V_C = 16 P_A V_A$. For a symmetric square process, this means dimensions scale by 4:

  • $A = (V_0, P_0)$
  • $B = (V_0, 4P_0)$ $\rightarrow T_B = 4T_0$
  • $C = (4V_0, 4P_0)$ $\rightarrow T_C = 16T_0$
  • $D = (4V_0, P_0)$ $\rightarrow T_D = 4T_0$

Coordinates of Points 1, 2, and 3:

  • Point 2: Intersection of the diagonal and the isotherm $PV = 4P_0V_0$. It is the geometric mean: $(2V_0, 2P_0)$.
    Check: $(2P_0)(2V_0) = 4P_0V_0$ (Matches Isotherm).
  • Point 1: Isochoric with $B$, Isobaric with $2$. Coords: $(V_0, 2P_0)$. Temperature $T_1 = 2T_0$.
  • Point 3: Isobaric with $D$, Isochoric with $2$. Coords: $(2V_0, P_0)$. Temperature $T_3 = 2T_0$.

2. Calculating Heat Received ($Q_{in}$)

Heat is received (positive $Q$) when temperature increases or volume expands (for isobaric). We analyze the modified cycle $1 \to B \to C \to D \to 3 \to 2 \to 1$.

  • Process $1 \to B$ (Isochoric Heating):
    $V = V_0$ (constant). $P$ increases $2P_0 \to 4P_0$.
    $Q_{1B} = n C_v \Delta T = \frac{3}{2} nR (T_B – T_1) = \frac{3}{2} nR (4T_0 – 2T_0) = \mathbf{3 nRT_0}$.
  • Process $B \to C$ (Isobaric Expansion):
    $P = 4P_0$ (constant). $V$ increases $V_0 \to 4V_0$.
    $Q_{BC} = n C_p \Delta T = \frac{5}{2} nR (T_C – T_B) = \frac{5}{2} nR (16T_0 – 4T_0) = \frac{5}{2} nR (12T_0) = \mathbf{30 nRT_0}$.
  • Process $C \to D$: Isochoric cooling (Heat rejected).
  • Process $D \to 3$: Isobaric compression (Heat rejected).
  • Process $3 \to 2$ (Isochoric Heating):
    $V = 2V_0$ (constant). $P$ increases $P_0 \to 2P_0$.
    $Q_{32} = n C_v \Delta T = \frac{3}{2} nR (T_2 – T_3) = \frac{3}{2} nR (4T_0 – 2T_0) = \mathbf{3 nRT_0}$.
  • Process $2 \to 1$: Isobaric compression (Heat rejected).

3. Comparison with Original Cycle ($ABCD$)

Heat received in modified cycle ($Q’$):

$$Q’ = Q_{1B} + Q_{BC} + Q_{32} = 3 + 30 + 3 = 36 nRT_0$$

Heat received in original cycle ($Q$):
In cycle ABCD, heat is received during $A \to B$ and $B \to C$.

  • $Q_{AB} = \frac{3}{2} nR (4T_0 – T_0) = 4.5 nRT_0$.
  • $Q_{BC} = 30 nRT_0$.
  • $Q = 34.5 nRT_0$.
Result: The ratio of heat received in the modified cycle to the original cycle is: $$ \frac{Q’}{Q} = \frac{36}{34.5} = \frac{72}{69} = \frac{24}{23} $$