Interaction Force: Dipole and Polarizable Molecule
1. Conceptual Analysis
The problem asks for the electrostatic force between a fixed dipole $\vec{p}_0$ and a neutral molecule with polarizability $\alpha$ located at a distance $r$ on the dipole’s axis.
The physics principles involved are:
- Electric Field of a Dipole: The fixed dipole creates a non-uniform electric field $\vec{E}$ at the location of the molecule.
- Induced Dipole Moment: The external field polarizes the molecule, inducing a dipole moment $\vec{p} = \alpha \vec{E}$.
- Force on a Dipole: A dipole in a non-uniform electric field experiences a net force given by $\vec{F} = (\vec{p} \cdot \nabla)\vec{E}$.
2. Electric Field of the Source Dipole
Consider the source dipole $\vec{p}_0$ placed at the origin, aligned along the $z$-axis (the axis of symmetry). The electric field on the axis at a distance $r$ is given by:
$$ \vec{E}(r) = \frac{2p_0}{4\pi\epsilon_0 r^3} \hat{r} $$Let $k = \frac{1}{4\pi\epsilon_0}$. Then,
$$ \vec{E}(r) = \frac{2k p_0}{r^3} \hat{r} $$3. Induced Dipole Moment
The molecule is polarized by this local field. Since $\alpha$ is positive, the induced dipole moment $\vec{p}$ is parallel to $\vec{E}$:
$$ \vec{p} = \alpha \vec{E} = \alpha \left( \frac{2k p_0}{r^3} \right) \hat{r} $$4. Calculation of the Force
The force on the induced dipole is the gradient of its potential energy, or more directly:
$$ \vec{F} = (\vec{p} \cdot \nabla) \vec{E} $$Since the setup is one-dimensional (radial), this simplifies to:
$$ F_r = p \frac{dE}{dr} $$Substituting the expressions for $p$ and $E$:
$$ F_r = \left( \frac{2\alpha k p_0}{r^3} \right) \cdot \frac{d}{dr} \left( \frac{2k p_0}{r^3} \right) $$Differentiating $E$ with respect to $r$:
$$ \frac{dE}{dr} = 2k p_0 \frac{d}{dr}(r^{-3}) = 2k p_0 (-3 r^{-4}) = -\frac{6k p_0}{r^4} $$Now, calculating the force:
$$ F_r = \left( \frac{2\alpha k p_0}{r^3} \right) \left( -\frac{6k p_0}{r^4} \right) $$ $$ F_r = – \frac{12 \alpha k^2 p_0^2}{r^7} $$The negative sign indicates that the force is attractive.
5. Final Result
Substituting $k = \frac{1}{4\pi\epsilon_0}$ back into the expression:
$$ |F| = 12 \alpha p_0^2 \left( \frac{1}{4\pi\epsilon_0} \right)^2 \frac{1}{r^7} $$ $$ |F| = \frac{12 \alpha p_0^2}{16 \pi^2 \epsilon_0^2 r^7} $$