tHERMAL ChYU 2

Solution – Kinetic Theory Expansion

Solution Analysis

Step 1: Analysis of Time Scales

First, we compare the time scale of the expansion process with the mean collision time of the balls.
The piston moves a distance $h = 1.0 \text{ m}$ with velocity $u = 1.0 \text{ m/s}$. The time taken for expansion is: $$ t_{exp} = \frac{h}{u} = \frac{1.0}{1.0} = 1.0 \text{ s} $$ The problem states the mean collision time of the balls is of the order of $10^3 \text{ s}$. $$ \tau_{coll} \approx 10^3 \text{ s} $$ Since $t_{exp} \ll \tau_{coll}$, the gas particles do not collide with each other during the expansion. This means there is no energy redistribution between the $x, y,$ and $z$ components of velocity. The degrees of freedom are independent. The expansion only affects the vertical motion.

$h$ $2h$ $\vec{u}$ $\vec{v}$ $v_y$ $v_x$ Only $v_y$ is affected by the moving piston.
Step 2: Dynamics of Vertical Motion ($y$-axis)

Consider the vertical component of velocity $v_y$. The rate of collision of a particle with the piston is given by $f = \frac{v_y}{2L}$, where $L$ is the instantaneous height.
For a piston moving away with speed $u$, the speed of the particle after reflection decreases by $2u$. $$ \Delta v_y = -2u $$ The rate of change of speed is: $$ \frac{dv_y}{dt} = f \cdot \Delta v_y = \left(\frac{v_y}{2L}\right)(-2u) = -\frac{v_y u}{L} $$ Since the piston velocity is $u = \frac{dL}{dt}$, we can write: $$ \frac{dv_y}{dL} = \frac{dv_y / dt}{dL / dt} = \frac{-v_y u / L}{u} = -\frac{v_y}{L} $$ Separating variables and integrating from initial state ($1$) to final state ($2$): $$ \int_{v_{y1}}^{v_{y2}} \frac{dv_y}{v_y} = -\int_{L_1}^{L_2} \frac{dL}{L} $$ $$ \ln\left(\frac{v_{y2}}{v_{y1}}\right) = -\ln\left(\frac{L_2}{L_1}\right) = \ln\left(\frac{L_1}{L_2}\right) $$ $$ v_{y2} = v_{y1} \left(\frac{L_1}{L_2}\right) $$ Given $L_1 = h$ and $L_2 = 2h$: $$ v_{y2} = v_{y1} \left(\frac{h}{2h}\right) = \frac{v_{y1}}{2} $$

Step 3: Energy Calculation

The total internal energy $U$ is the sum of kinetic energies associated with the $x, y,$ and $z$ components. Initially, the random motion implies the energy is equipartitioned: $$ U_{initial} = K_x + K_y + K_z $$ $$ K_x = K_y = K_z = \frac{U_{initial}}{3} $$ In the final state:

  • Horizontal components ($v_x, v_z$) are unchanged because there are no collisions and vertical walls are stationary. Hence, $K’_x = K_x$ and $K’_z = K_z$.
  • Vertical component ($v_y$) is halved ($v_{y2} = v_{y1}/2$). Kinetic energy is proportional to $v^2$, so: $$ K’_y \propto v_{y2}^2 = \left(\frac{v_{y1}}{2}\right)^2 = \frac{v_{y1}^2}{4} \implies K’_y = \frac{K_y}{4} $$
The total final internal energy is: $$ U_{final} = K’_x + K’_y + K’_z $$ $$ U_{final} = \frac{U_{initial}}{3} + \frac{1}{4}\left(\frac{U_{initial}}{3}\right) + \frac{U_{initial}}{3} $$ $$ U_{final} = U_{initial} \left( \frac{1}{3} + \frac{1}{12} + \frac{1}{3} \right) $$ $$ U_{final} = U_{initial} \left( \frac{4}{12} + \frac{1}{12} + \frac{4}{12} \right) = U_{initial} \left( \frac{9}{12} \right) $$ $$ U_{final} = \frac{3}{4} U_{initial} $$

Ratio of total internal energy in the new steady state to that of the initial state is: $$ \frac{U_{final}}{U_{initial}} = \frac{3}{4} $$